tert-Butyl 4-chloro-3-oxobutyrate → t-butyl-4-chloro-3(R)-hydroxybutyrate
반응식
[C:1]([O:5][C:6](=[O:12])[CH2:7][C:8]([CH2:10][Cl:11])=[O:9])([CH3:4])([CH3:3])[CH3:2]>C(Cl)(Cl)Cl>[C:1]([O:5][C:6](=[O:12])[CH2:7][C@@H:8]([OH:9])[CH2:10][Cl:11])([CH3:4])([CH3:2])[CH3:3]참가 물질
3
실험 절차
The procedure of example 369 was repeated using t-butyl-4-chloroacetoacetate as the substrate to give t-butyl-4-chloro-3(R)-hydroxybutyrate, [α]D23 +18.09° (c, 5.1 CHCl3).
출처 및 근거
- ORD 기록
- ord-0d3f64c793854208b49b525f022d5a94
- 출처 데이터셋
- uspto-grants-1987_12
- 특허 번호
- US04710468
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