Hydrochloric Acid → HCID 18798338, compound

HRID 1003802Notes

Reaction equation

HRID 1003802 reaction equation
[OH-:1].[Na+].[CH2:3](O)[CH3:4].C1(N=[C:13]([OH:75])[C:14]2[C:15](=[C:19]([O:55][C:56]3[CH:61]=[CH:60][C:59]([O:62][CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68]CCCCCC)=[CH:58][CH:57]=3)[C:20](=[C:24]([C:34]=2[O:35][C:36]2[CH:41]=[CH:40][C:39]([O:42][CH2:43][CH2:44][CH2:45][CH2:46]CCCCCCCC)=[CH:38][CH:37]=2)[C:25](=NC2C=CC=CC=2)[OH:26])[C:21]([OH:23])=[O:22])[C:16]([OH:18])=[O:17])C=CC=CC=1.Cl.[OH2:77]>>[CH2:43]([O:42][C:39]1[CH:38]=[CH:37][C:36]([O:35][C:34]2[C:14]([C:13]([OH:1])=[O:75])=[C:15]([C:16]([OH:18])=[O:17])[C:19]([O:55][C:56]3[CH:57]=[CH:58][C:59]([O:62][CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68][CH2:38][CH2:37][CH2:36][CH2:41][CH2:3][CH3:4])=[CH:60][CH:61]=3)=[C:20]([C:21]([OH:23])=[O:22])[C:24]=2[C:25]([OH:26])=[O:77])=[CH:41][CH:40]=1)[CH2:44][CH2:45][CH2:46][CH2:25][CH2:24][CH2:34][CH2:14][CH2:15][CH2:19][CH2:20][CH3:21]

Participants

6

Reactant 5

HCID 313Hydrochloric AcidHCID 702EthanolHCID 962WaterHCID 14798Sodium HydroxideHCID 136404652HCID 136404652, compound

Product 1

HCID 18798338HCID 18798338, compound

Procedure

Into 150 ml of 10% NaOH solution made from 1:1 (v:v) mixture of ethanol and water were dissolved 2 g of N,N'-diphenyl-3,6-bis[4-(n-dodecyloxy)phenyloxy]pyromellitic diimide obtained from above. This solution was refluxed for 72 hr under nitrogen atmosphere and then cooled to ambient temperature. When it was neutralized with 5% aqueous HCl, white precipitates were formed. These precipitates were filtered, air-dried and recrystallized from 1:1 (v:v) mixture of hexane and ethyl acetate to obtain 3,6-bis[4-(n-dodecyloxy)phenyloxy]pyromellitic acid.

Workup

  1. customobtained from above
  2. temperatureThis solution was refluxed for 72 hr under nitrogen atmosphere
  3. customwhite precipitates
  4. customwere formed
  5. filtrationThese precipitates were filtered
  6. customair-dried
  7. customrecrystallized from 1:1 (v:v) mixture of hexane and ethyl acetate

Sources & evidence

ORD record
ord-dcb247348ae5496db88ecf4f3a4d5f5e
Source dataset
uspto-grants-2000_04
Patent number
US06046342

Reaction notes

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