HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Acetate → HCID 18790891, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Acetate | HCID 517045 | — |
| Reactant | HCID 18790894 | HCID 18790894 | — |
| Reactant | HCID 178418287 | HCID 178418287 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 18790891 | HCID 18790891 | 88% |
Reaction Steps
A solution of 2-butyl-7-(tert-butyldimethylsilyloxy)-1-heptanol in dichloromethane (10 ml) was added to a suspension of pyridinium chlorochromate (8.09 g, 38 mmol) and sodium acetate (150 mg) in 30 ml of dichloromethane and stirred at ambient temperature for several hours. After the usual work up followed by PMPLC, 6.61 g (88%) of 2-butyl-7-(tert-butyldimethylsilyloxy)heptanaI was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06054141 |
| Source dataset | uspto-grants-2000_04 |
| ORD ID | ord-50fe6a3c57db42ccbdfb0a9c3b6d0595 |
| Source note | uspto-grants-2000_04 |