Acetate → HCID 18790895, compound

HRID 1005263Notes

Reaction equation

HRID 1005263 reaction equation
[CH2:1]([CH:5]([CH:12]=[CH2:13])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][OH:11])[CH2:2][CH2:3][CH3:4].[C:14]([O-])(=[O:16])[CH3:15].C(OC(=O)C)(=O)C>CN(C)C1C=CN=CC=1.N1C=CC=CC=1>[C:14]([O:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH:5]([CH2:1][CH2:2][CH2:3][CH3:4])[CH:12]=[CH2:13])(=[O:16])[CH3:15]

Participants

6

Reactant 3

HCID 175AcetateHCID 7918Acetic AnhydrideHCID 18790896HCID 18790896, compound

Product 1

HCID 18790895HCID 18790895, compoundYield 93%

Reagents, catalysts & solvents 2

HCID 142844-(Dimethylamino)pyridineCatalystHCID 1049PyridineSolvent

Procedure

6- Butyloct-7-en-1-ol (800 mg, 4.34 mmol) was converted to the acetate in a standard procedure with acetic anhydride, pyridine and 4-dimethylaminopyridine (DMAP). Subsequent purification by PMLPC yielded 914 mg (93%) of 6-butyloct-7-en-1-yl acetate.

Workup

  1. customSubsequent purification by PMLPC

Sources & evidence

ORD record
ord-25519c0b70ff473fba9b7fe1f612700e
Source dataset
uspto-grants-2000_04
Patent number
US06054141

Reaction notes

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