4-Amino-3-nitrobenzophenone → HCID 22668940, compound

HRID 1007199Notes

Reaction equation

HRID 1007199 reaction equation
[Cl:1][C:2]1[CH:10]=[CH:9][C:5]([C:6](Cl)=[O:7])=[CH:4][N:3]=1.[NH2:11][C:12]1[CH:25]=[CH:24][C:15]([C:16]([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[O:17])=[CH:14][C:13]=1[N+:26]([O-:28])=[O:27]>>[Cl:1][C:2]1[N:3]=[CH:4][C:5]([C:6]([NH:11][C:12]2[CH:25]=[CH:24][C:15]([C:16](=[O:17])[C:18]3[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=3)=[CH:14][C:13]=2[N+:26]([O-:28])=[O:27])=[O:7])=[CH:9][CH:10]=1

Participants

3

Reactant 2

HCID 5969704-Amino-3-nitrobenzophenoneHCID 27821656-Chloronicotinoyl Chloride

Product 1

HCID 22668940HCID 22668940, compound

Procedure

The title compound was prepared from 6-chloronicotinoyl chloride and 4-amino-3-nitrobenzophenone and was obtained as a yellow solid as described in Example 1. 1H NMR (CDCl3): 11.61 (bs, 1H), 9.12 (d, J=8.7, 1H), 9.06 (d, J=2.4, 1H), 8.79 (d, J=1.8, 1H), 8.28-8.25 (m, 1H), 8.23-8.19 (m, 1H), 7.82-7.81 (m, 1H), 7.80-7.79 (m, 1H), 7.67-7.64 (m, 1H), 7.58-7.53 (m, 3H).

Workup

  1. customwas obtained as a yellow solid

Sources & evidence

ORD record
ord-025f0dd9b3b4439ab1f86eb5a832973f
Source dataset
uspto-grants-2004_09
Patent number
US06794397B2

Reaction notes

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