6-Nitro-2,4-xylidine → HCID 9857686, compound

HRID 1007221Notes

Reaction equation

HRID 1007221 reaction equation
[Cl:1][C:2]1[CH:10]=[CH:9][C:5]([C:6](Cl)=[O:7])=[CH:4][N:3]=1.[N+:11]([C:14]1[CH:20]=[C:19]([CH3:21])[CH:18]=[C:17]([CH3:22])[C:15]=1[NH2:16])([O-:13])=[O:12]>>[Cl:1][C:2]1[N:3]=[CH:4][C:5]([C:6]([NH:16][C:15]2[C:17]([CH3:22])=[CH:18][C:19]([CH3:21])=[CH:20][C:14]=2[N+:11]([O-:13])=[O:12])=[O:7])=[CH:9][CH:10]=1

Participants

3

Reactant 2

HCID 742196-Nitro-2,4-xylidineHCID 27821656-Chloronicotinoyl Chloride

Product 1

HCID 9857686HCID 9857686, compound

Procedure

The title compound was prepared from 6-chloronicotinoyl chloride and 2-nitro-4,6-dimethylaniline as a light yellow solid as described in Example 1. 1H NMR (CDCl3): 9.09 (s, 1H), 8.97 (d, J=2.4, 1H), 8.22-8.18 (m, 1H), 7.60 (d, J=1.2, 1H), 7.50 (d, J=8.1, 1H), 7.42 (s, 1H), 2.43 (s, 3H), 2.35 (s, 3H).

Sources & evidence

ORD record
ord-71d6dbfa9bdb4feb8c1a5aedcf183925
Source dataset
uspto-grants-2004_09
Patent number
US06794397B2

Reaction notes

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