Hydrochloric Acid → HCID 86759534, compound

HRID 1008107Notes

Reaction equation

HRID 1008107 reaction equation
[C:1]([C:3]1[CH:8]=[CH:7][C:6]([S:9][CH2:10][C:11]([O:13][CH2:14][CH2:15][O:16][CH2:17][CH3:18])=[O:12])=[CH:5][CH:4]=1)#[N:2].[Al](Br)(Br)Br.[Cl:23][C:24]([Cl:28])([Cl:27])[C:25]#[N:26].[ClH:29]>>[Cl:23][C:24]([Cl:28])([Cl:27])[C:25]1[N:26]=[C:25]([C:24]([Cl:27])([Cl:23])[Cl:29])[N:26]=[C:1]([C:3]2[CH:4]=[CH:5][C:6]([S:9][CH2:10][C:11]([O:13][CH2:14][CH2:15][O:16][CH2:17][CH3:18])=[O:12])=[CH:7][CH:8]=2)[N:2]=1

Participants

5

Reactant 4

HCID 313Hydrochloric AcidHCID 11011TrichloroacetonitrileHCID 24409Aluminum bromideHCID 22666607HCID 22666607, compound

Product 1

HCID 86759534HCID 86759534, compound

Procedure

The mixed solution of 10 g of 2-ethoxyethyl 2-(4-cyanophenylthio)acetate (37.7 mmol), 0.8 g of AlBr3, and 50 g of trichloroacetonitrile was bubbled with dry HCl at room temperature.

Sources & evidence

ORD record
ord-3d387ecc0c7f4f3188f27efb19d7b3ba
Source dataset
uspto-grants-2004_09
Patent number
US06797739B1

Reaction notes

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