Hydrochloric Acid → HCID 86622839, compound

HRID 1008108Notes

Reaction equation

HRID 1008108 reaction equation
[C:1]([C:3]1[CH:8]=[CH:7][C:6]([S:9][CH2:10][C:11]([O:13][CH:14]2[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]2)=[O:12])=[CH:5][CH:4]=1)#[N:2].[Al](Br)(Br)Br.[Cl:24][C:25]([Cl:29])([Cl:28])[C:26]#[N:27].[ClH:30]>>[Cl:24][C:25]([Cl:29])([Cl:28])[C:26]1[N:27]=[C:26]([C:25]([Cl:28])([Cl:24])[Cl:30])[N:27]=[C:1]([C:3]2[CH:4]=[CH:5][C:6]([S:9][CH2:10][C:11]([O:13][CH:14]3[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]3)=[O:12])=[CH:7][CH:8]=2)[N:2]=1

Participants

5

Reactant 4

HCID 313Hydrochloric AcidHCID 11011TrichloroacetonitrileHCID 24409Aluminum bromideHCID 22666604HCID 22666604, compound

Product 1

HCID 86622839HCID 86622839, compound

Procedure

The mixed solution of 10 g of cyclohexyl 2-(4-cyanophenylthio)acetate (36.3 mmol), 0.8 g of AlBr3, and 50 g of trichloroacetonitrile was bubbled with dry HCl at room temperature.

Sources & evidence

ORD record
ord-f9e8c450290a44cfbc2af3fdc9168d63
Source dataset
uspto-grants-2004_09
Patent number
US06797739B1

Reaction notes

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