Hydrochloric Acid → HCID 86759535, compound

HRID 1008109Notes

Reaction equation

HRID 1008109 reaction equation
[C:1]([C:3]1[CH:8]=[CH:7][C:6]([S:9][CH2:10][C:11]([O:13][CH2:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[O:12])=[CH:5][CH:4]=1)#[N:2].[Al](Br)(Br)Br.[Cl:25][C:26]([Cl:30])([Cl:29])[C:27]#[N:28].[ClH:31]>>[Cl:25][C:26]([Cl:30])([Cl:29])[C:27]1[N:28]=[C:27]([C:26]([Cl:29])([Cl:25])[Cl:31])[N:28]=[C:1]([C:3]2[CH:4]=[CH:5][C:6]([S:9][CH2:10][C:11]([O:13][CH2:14][C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=3)=[O:12])=[CH:7][CH:8]=2)[N:2]=1

Participants

5

Reactant 4

HCID 313Hydrochloric AcidHCID 11011TrichloroacetonitrileHCID 24409Aluminum bromideHCID 22666601HCID 22666601, compound

Product 1

HCID 86759535HCID 86759535, compound

Procedure

The mixed solution of 10 g of benzyl 2-(4-cyanophenylthio)acetate (35.3 mmol), 0.8 g of AlBr3, and 50 g of trichloroacetonitrile was bubbled by dry HCl at room temperature.

Sources & evidence

ORD record
ord-c2f0627ad9364086ba03d93b675d57ed
Source dataset
uspto-grants-2004_09
Patent number
US06797739B1

Reaction notes

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