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HRID1013435

反应详情

EQUATION

反应方程式

HRID 1013435 的结构方程式

REACTANTS

反应物

1
结构：CC(C)(C)OC(=O)CC[C@H](NC(=O)CCOc1no[n+]([O-])c1S(=O)(=O)c1ccccc1)C(=O)OC(C)(C)C
HCID67317279

未命名化合物

PRODUCTS

生成物

1
结构：O=C(O)CC[C@H](NC(=O)CCOc1no[n+]([O-])c1S(=O)(=O)c1ccccc1)C(=O)O
HCID57626191

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：ClCCl
溶剂HCID6344

Dichloromethane

CH2Cl2

结构：O=C(O)C(F)(F)F
溶剂HCID6422

未命名化合物

PROCEDURE

实验过程

A solution of the compound obtained in Step A (3 g-5.5 mmol) in 100 ml of dichloromethane and 15 ml of TFA is stirred for 6 hours under argon. The solvents are distilled off in vacuo. The residue is triturated in diisopropyl ether, filtered off with suction and then dried in vacuo to yield the expected product in the form of white crystals.

WORKUP

后处理

  1. distillationThe solvents are distilled off in vacuo
  2. customThe residue is triturated in diisopropyl ether
  3. filtrationfiltered off with suction
  4. customdried in vacuo