Isopropanol → HCID 178457300, compound

HRID 1014911Notes

Reaction equation

HRID 1014911 reaction equation
[C:1]([S:14]([N:17]([CH2:21][CH2:22][CH2:23][C:24]([O:26]C)=[O:25])[CH2:18][CH2:19][CH3:20])(=[O:16])=[O:15])([C:4]([C:7]([C:10]([F:13])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2].[OH-].[K+:29].C(O)(C)C>O>[C:1]([S:14]([N:17]([CH2:21][CH2:22][CH2:23][C:24]([O:26][K:29])=[O:25])[CH2:18][CH2:19][CH3:20])(=[O:16])=[O:15])([C:4]([C:7]([C:10]([F:13])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2]

Participants

5

Reactant 3

HCID 3776IsopropanolHCID 14797Potassium HydroxideHCID 131726673HCID 131726673, compound

Product 1

HCID 178457300HCID 178457300, compoundYield 163.2%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A round bottom flask fitted with a heating mantle and an overhead stirrer was charged with C4F9SO2N(C3H7)CH2CH2CH2COOCH3 (63.0 g; 0.143 mole), KOH (11.0 g; 0.196 mole; pellets) isopropanol (22 ml.) and deionized water (18 mL). The ensuing mixture was refluxed overnight, cooled to room temperature, yielding a solution of C4F9SO2N(C3H7)CH2CH2CH2COOK (108.6 g; 53.4% solids).

Workup

  1. customA round bottom flask fitted with a heating mantle and an overhead stirrer
  2. temperatureThe ensuing mixture was refluxed overnight

Sources & evidence

ORD record
ord-312b8e79e5bc49ddba674c160a300f92
Source dataset
uspto-grants-2011_07
Patent number
US07985723B2

Reaction notes

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