Nitromethane → 4-(2-Nitroethenyl)-2H-1,3-benzodioxole

HRID 1015001Notes

Reaction equation

[O:1]1[C:5]2[CH:6]=[CH:7][CH:8]=[C:9]([CH:10]=O)[C:4]=2[O:3][CH2:2]1.[N+:12]([CH3:15])([O-:14])=[O:13]>>[N+:12]([CH:15]=[CH:10][C:9]1[C:4]2[O:3][CH2:2][O:1][C:5]=2[CH:6]=[CH:7][CH:8]=1)([O-:14])=[O:13]

Participants

Reactant 2

HCID 6375Nitromethane

HCID 822641,3-Benzodioxole-4-carboxaldehyde

Product 1

HCID 545432424-(2-Nitroethenyl)-2H-1,3-benzodioxole

Procedure

In close analogy to the procedure described above, Benzo[1,3]dioxole-4-carbaldehyde is reacted with nitromethane to provide the title compound.

Sources & evidence

ORD record: ord-24eb5a5dc9e14b7dbd632195b9da0f04
Source dataset: uspto-grants-2011_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07985753B2

Reaction notes

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