HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 69958659, compound → HCID 18407017, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 69958659 | HCID 69958659 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium hydroxide | HCID 9942167 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 18407017 | HCID 18407017 | 108.6% |
Reaction Steps
A solution of 2.7 g of 1-benzyl-4-benzylidene-3-methyl-piperidine and 2 g of 20% palladium hydroxide on carbon in 125 mL of ethanol was shaken 3 days under 55 psi of hydrogen. The catalyst was filtered off and the solution concentrated to give 2 g of a mixture of cis and trans-4-benzyl-3-methyl-piperidine as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06476041B1 |
| Source dataset | uspto-grants-2002_11 |
| ORD ID | ord-1536bdac76ac4efd8505b344a76dcc25 |
| Source note | uspto-grants-2002_11 |