HCID 512824, compound → HCID 512842, compound

HRID 1016521Notes

Reaction equation

HRID 1016521 reaction equation
[CH2:1]([N:10]1[C:15](=[O:16])[CH:14]=[C:12]([CH3:13])[C:11]1=[O:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]C>[Pd].CO>[CH3:13][CH:12]1[CH2:14][C:15](=[O:16])[N:10]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])[C:11]1=[O:17]

Participants

4

Reactant 1

HCID 512824HCID 512824, compound

Product 1

HCID 512842HCID 512842, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

10% Palladium on carbon catalyst (5 wt %) was added to a stirred solution of N-nonyl citraconimide (0.02 M) prepared as described in Example 5 above in methanol (100 ml). Hydrogen gas was bubbled through this solution for three hours. The solution was then filtered over celite and concentrated in vacuo. Chromatography over silica gel gave the desired product.

Workup

  1. customprepared
  2. customHydrogen gas was bubbled through this solution for three hours
  3. filtrationThe solution was then filtered over celite and
  4. concentrationconcentrated in vacuo

Sources & evidence

ORD record
ord-45cdda42417148d89a504e99b7aa8a56
Source dataset
uspto-grants-2002_11
Patent number
US06476053B1

Reaction notes

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