Pyrazole → HCID 131731360, compound

HRID 1019463Notes

Reaction equation

[NH:1]1[CH:5]=[CH:4][CH:3]=[N:2]1.[Li+:6].[C:7]([S:11]([N-:14][S:15]([C:18]([F:21])([F:20])[F:19])(=[O:17])=[O:16])(=[O:13])=[O:12])([F:10])([F:9])[F:8]>>[NH:1]1[CH:5]=[CH:4][CH:3]=[N:2]1.[Li+:6].[C:18]([S:15]([N-:14][S:11]([C:7]([F:10])([F:9])[F:8])(=[O:13])=[O:12])(=[O:16])=[O:17])([F:20])([F:19])[F:21]

Participants

Reactant 2

HCID 1048Pyrazole

HCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanide

Product 1

HCID 131731360HCID 131731360, compoundYield 137.4%

Conditions

Temperature: 30 °C

Procedure

2.13 g of purified pyrazole and 3 g of LiTFSI were put into a round bottom flask and slowly stirred for 5 hours under a nitrogen circumstance of 30° C., thereby obtaining 5.1 g of pyrazole-LiTFSI eutectic mixture.

Sources & evidence

ORD record: ord-5deaa066f335434bad96507e8dfca8df
Source dataset: uspto-grants-2014_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08715866B2

Reaction notes

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