Dimethyl N-cyanodithioiminocarbonate → HCID 178503898, compound

HRID 1022833Notes

Reaction equation

HRID 1022833 reaction equation
[C:1]([N:3]=[C:4](SC)[S:5][CH3:6])#[N:2].[CH2:9]([NH2:19])[C:10]1[CH:18]=[CH:17][C:16]2[O:15][CH2:14][O:13][C:12]=2[CH:11]=1>CO>[O:15]1[C:16]2[CH:17]=[CH:18][C:10]([CH2:9][NH:19][C:4](=[N:3][C:1]#[N:2])[S:5][CH3:6])=[CH:11][C:12]=2[O:13][CH2:14]1

Participants

4

Reactant 2

HCID 66289Dimethyl N-cyanodithioiminocarbonateHCID 75799Benzo-1,3-dioxole-5-methylamine

Product 1

HCID 178503898HCID 178503898, compoundYield 95%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

1.6 g (10.94 mmol) of dimethyl cyanocarbonodithioimidate and 2.0 g (13.23 mmol) of piperonyl amine were dissolved in methyl alcohol, and then stirred for 30 minutes. After completion of the reaction, the produced solid was filtered, and then washed with water and methyl alcohol, thus obtaining 2.4 g (95% yield) of a desired compound of Formula 3.

Workup

  1. customAfter completion of the reaction
  2. filtrationthe produced solid was filtered
  3. washwashed with water and methyl alcohol

Sources & evidence

ORD record
ord-e03ebf047c90496abd7dd657bccab0f9
Source dataset
uspto-grants-2014_05
Patent number
US08722674B2

Reaction notes

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