Water → HCID 87329530, compound

HRID 1024123Notes

Reaction equation

HRID 1024123 reaction equation
[CH:1]([C:4]([C:7]([C:10]([C:13]([C:16]([CH2:19][S:20]([OH:22])=[O:21])([F:18])[F:17])([F:15])[F:14])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2].[OH2:23].BrBr>C(O)(=O)C>[CH:1]([C:4]([C:7]([C:10]([C:13]([C:16]([CH2:19][S:20]([OH:23])(=[O:22])=[O:21])([F:17])[F:18])([F:15])[F:14])([F:11])[F:12])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2]

Participants

5

Reactant 3

HCID 962WaterHCID 24408BromineHCID 131731388HCID 131731388, compound

Product 1

HCID 87329530HCID 87329530, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

H(CF2)6CH2SO2H (1.00 g, 2.63 mmol) was put in a 100 ml flask, and was dissolved in acetic acid (20 ml) in the air. After the reaction system was dipped in ice bath and water (1.0 ml) was added thereto, bromine (1.1 g, 6.84 mmol) was added and stirring was continued at room temperature for 12 hours. After completion of the reaction, the inside of the system was brought to reduced pressure, and after removing the solvent and bromine, the reaction product was dried in vacuo at 60° C. for 12 hours to obtain H(CF2)6CH2SO3H (1.04 g, 2.63 mmol).

Workup

  1. customAfter completion of the reaction
  2. customafter removing the solvent and bromine
  3. customthe reaction product was dried in vacuo at 60° C. for 12 hours

Sources & evidence

ORD record
ord-0e69d35bd89e44b78d71c34da144cbaf
Source dataset
uspto-grants-2014_05
Patent number
US08722809B2

Reaction notes

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