Ammonia → HCID 10399099, compound

HRID 1029793Notes

Reaction equation

HRID 1029793 reaction equation
[S:1]1[CH2:4][S:3][C:2]1=[C:5]([C:12](C(OOCC)=O)=[O:13])[C:6]([O:8][CH:9]([CH3:11])[CH3:10])=[O:7].[NH3:20]>>[S:1]1[CH2:4][S:3][C:2]1=[C:5]([C:12](=[O:13])[NH2:20])[C:6]([O:8][CH:9]([CH3:11])[CH3:10])=[O:7]

Participants

3

Reactant 2

HCID 222AmmoniaHCID 19901120HCID 19901120, compound

Product 1

HCID 10399099HCID 10399099, compound

Procedure

A solution of isopropyl 2-(1,3-dithietan-2-ylidene)-2-(ethoxycarboxycarbonyl)acetate (10 g) in methanolic ammonia (60 ml) was stirred at room temperature for 4 hrs. The mixture was concentrated and purified with n-hexane and ethyl ether to give the titled compound as a white solid. (5.2 g, 68%)

Workup

  1. concentrationThe mixture was concentrated
  2. custompurified with n-hexane and ethyl ether

Sources & evidence

ORD record
ord-5ad66801fdd64f3a85a2d015dc0df679
Source dataset
uspto-grants-1992_04
Patent number
US05103013

Reaction notes

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