Perfluorohept-1-ene → HCID 14364319, compound

HRID 1030022Notes

Reaction equation

HRID 1030022 reaction equation
[H][H].[F:3][C:4]([F:23])=[C:5]([F:22])[C:6]([F:21])([F:20])[C:7]([F:19])([F:18])[C:8]([F:17])([F:16])[C:9]([F:15])([F:14])[C:10]([F:13])([F:12])[F:11]>>[F:3][CH:4]([F:23])[C:5]([F:22])([C:5]([F:22])([CH:4]([F:3])[F:23])[C:6]([F:21])([F:20])[C:7]([F:19])([F:18])[C:8]([F:17])([F:16])[C:9]([F:15])([F:14])[C:10]([F:13])([F:12])[F:11])[C:6]([F:20])([F:21])[C:7]([F:18])([F:19])[C:8]([F:16])([F:17])[C:9]([F:15])([F:14])[C:10]([F:13])([F:12])[F:11]

Participants

3

Reactant 2

HCID 67737Perfluorohept-1-eneHCID 178418361HCID 178418361, compound

Product 1

HCID 14364319HCID 14364319, compound

Procedure

A stream of hydrogen (30 ml/min) saturated with perfluoro-1-heptene was passed into the photoreactor and photolyzed for 25 hours. 5.7 g of crude product consisted of a mixture of dimers (GC-MS) whose major component (55%) was the title compound, which shows the characteristic CF2H-CFRR' moiety by 1H-NMR (in d6 -acetone: 6.30 8;J1H-F =51.5 Hz, J2H-F =4.5 Hz).

Sources & evidence

ORD record
ord-b4b655da453b4038b652c488cad5f90d
Source dataset
uspto-grants-1992_04
Patent number
US05104503

Reaction notes

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