1-Heptene, 1,1,2,3,3,4,4,5,5,6,6,7,7,7-tetradecafluoro- → HCID 14364319, compound

Participants

Reaction Steps

A stream of hydrogen (30 ml/min) saturated with perfluoro-1-heptene was passed into the photoreactor and photolyzed for 25 hours. 5.7 g of crude product consisted of a mixture of dimers (GC-MS) whose major component (55%) was the title compound, which shows the characteristic CF2H-CFRR' moiety by 1H-NMR (in d6 -acetone: 6.30 8;J1H-F =51.5 Hz, J2H-F =4.5 Hz).

Provenance & Evidence