Hydrogen Sulfide → 3,5-Di-tert-butyl-4-hydroxyphenyl dithiocarbamate

HRID 1030225Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1030225
[C:1]([C:5]1[CH:6]=[C:7]([S:16][C:17]#[N:18])[CH:8]=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:10]=1[OH:11])([CH3:4])([CH3:3])[CH3:2].C(N(CC)CC)C.[SH2:26]>C(OCC)C>[C:17](=[S:26])([S:16][C:7]1[CH:6]=[C:5]([C:1]([CH3:4])([CH3:2])[CH3:3])[C:10]([OH:11])=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[CH:8]=1)[NH2:18]

Komponenten

5

Edukt 3

HCID 402Hydrogen SulfideHCID 8471TriethylamineHCID 6192452,6-DI-Tert-butyl-4-thiocyanato-phenol

Produkt 1

HCID 198222993,5-Di-tert-butyl-4-hydroxyphenyl dithiocarbamate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

3,5-Di-tert-butyl-4-hydroxyphenyl thiocyanate (8.7 g) and 0.3 g of triethylamine were dissolved in 80 ml of diethyl ether, and hydrogen sulfide was blown into the solution at room temperature over 4.5 hours. The reaction mixture was concentrated, and the crude product thus obtained was washed with diethyl ether to give 7.5 g of the desired compound as a colorless solid.

Aufarbeitung

  1. concentrationThe reaction mixture was concentrated
  2. customthe crude product thus obtained
  3. washwas washed with diethyl ether

Quellen und Nachweise

ORD-Eintrag
ord-f36eeb5821fc47d0bea9d53a851b063b
Quelldatensatz
uspto-grants-1992_04
Patentnummer
US05104889

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