反应详情

Into a fritted column was added: 12 g (12 meq H+) ion exchange resin (Amberlite® IR 120 brand). Resin beads were washed with 100 ml deionized water. Into a 50 ml beaker were added: 8.6 g (10 meq) sodium dodecyl benzene sulfonate (Biosoft D-40 brand), 7 g water, and 7 g isopropanol. The Biosoft D-40 solution was run through the column and collected in a 100 ml beaker containing: 0.58 g (12 meq Cu) copper hydroxide mixture and 20 g water. The effluent/copper hydroxide mixture was swirl mixed while collecting the effluent. A 10 g water rinse of the column was added to the copper mixture. Extraction of the beaker's contents was done with 2×25 ml toluene. The toluene solubles were dried with molecular sieve. Stripping, on a rotary evaporator removed the toluene, and the resulting solids were vacuum dried overnight at room temperature.

1. additionInto a fritted column was added
2. washResin beads were washed with 100 ml
3. additionInto a 50 ml beaker were added
4. customcollected in a 100 ml beaker
5. additioncontaining
6. customwhile collecting the effluent
7. washA 10 g water rinse of the column
8. additionwas added to the copper mixture
9. extractionExtraction of the beaker's contents
10. dry with materialThe toluene solubles were dried with molecular sieve
11. customStripping, on a rotary evaporator
12. customremoved the toluene
13. customdried overnight at room temperature