Chlorine → HCID 14460365, compound

HRID 1031045Notes

Reaction equation

HRID 1031045 reaction equation
[Cl:1]Cl.[N:3]([CH2:6][C:7]([CH3:35])([CH3:34])[C:8](=[O:33])[CH:9]([N:23]1[CH:26](SC(C)(C)C)[CH2:25][C:24]1=[O:32])[C:10]([O:12][CH2:13][C:14]1[CH:19]=[CH:18][C:17]([N+:20]([O-:22])=[O:21])=[CH:16][CH:15]=1)=[O:11])=[N+:4]=[N-:5]>C(Cl)(Cl)(Cl)Cl.C(Cl)Cl>[N:3]([CH2:6][C:7]([CH3:35])([CH3:34])[C:8](=[O:33])[CH:9]([N:23]1[CH:26]([Cl:1])[CH2:25][C:24]1=[O:32])[C:10]([O:12][CH2:13][C:14]1[CH:19]=[CH:18][C:17]([N+:20]([O-:22])=[O:21])=[CH:16][CH:15]=1)=[O:11])=[N+:4]=[N-:5]

Participants

5

Reactant 2

HCID 24526ChlorineHCID 14460323HCID 14460323, compound

Product 1

HCID 14460365HCID 14460365, compound

Reagents, catalysts & solvents 2

HCID 5943Carbon TetrachlorideSolventHCID 6344DichloromethaneSolvent2×

Procedure

286 μl of a solution of chlorine in carbon tetrachloride containing 1.14 g/10 ml is added at -60° C. to a solution of 110 mg of p-nitrobenzyl 5-azido-2-(4-tert-butylthio-2-oxo-1-azetidinyl)-4,4-dimethyl-3-oxopentanoate in 9 ml of methylene chloride. The reaction solution is evaporated in a rotary evaporator, 119 mg of yellow oil being obtained. IR spectrum in CH2Cl2 : 2930, 2860, 2105, 1780, 1755, 1720, 1610, 1530, 1350, 1190 cm-1.

Workup

  1. customThe reaction solution is evaporated in a rotary evaporator, 119 mg of yellow oil
  2. custombeing obtained

Sources & evidence

ORD record
ord-046ad0bb02bb433b86cb7ecdad8de9da
Source dataset
uspto-grants-1992_04
Patent number
US05108747

Reaction notes

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