Nitric Acid → HCID 3015351, compound

HRID 1031417Notes

Reaction equation

HRID 1031417 reaction equation
[CH2:1]([N:3]([CH2:6][CH3:7])[CH2:4][CH3:5])[CH3:2].[N+:8]([O-:11])([OH:10])=[O:9]>>[N+:8]([O-:11])([O-:10])=[O:9].[CH2:1]([NH+:3]([CH2:6][CH3:7])[CH2:4][CH3:5])[CH3:2]

Participants

3

Reactant 2

HCID 944Nitric AcidHCID 8471Triethylamine

Product 1

HCID 3015351HCID 3015351, compoundYield 11%

Procedure

Ceric hydroxide (10.4 gm, 50 mmole) was dissolved in 35 ml of nitric acid with heating. The solution was allowed to cool slightly and triethylamine (20.9 ml, 150 mmole) was added dropwise over a period of about 5 minutes. The resulting reaction mixture was stirred at room temperature for 3 hours and then cooled in an ice bath. The resulting orange precipitate was filtered, washed quickly with deionized water, and recrystallized from hot water to give 4 gm of orange solid, mp 135° C. (yield 11%)

Workup

  1. temperaturewith heating
  2. temperatureto cool slightly
  3. customThe resulting reaction mixture
  4. temperaturecooled in an ice bath
  5. filtrationThe resulting orange precipitate was filtered
  6. washwashed quickly with deionized water
  7. customrecrystallized from hot water

Sources & evidence

ORD record
ord-901a6858100845ac8a970884d0750b8d
Source dataset
uspto-grants-1990_09
Patent number
US04954451

Reaction notes

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