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HRID1031427

反应详情

EQUATION

反应方程式

HRID 1031427 的结构方程式

REACTANTS

反应物

2
结构：NN.O
HCID24654

Hydrazine hydrate (1:1)

H6N2O

结构：CC(CC(=O)O)C(=O)c1ccc(Cl)c([N+](=O)[O-])c1
HCID2874446

4-Chloro-β-methyl-3-nitro-γ-oxobenzenebutanoic acid

C11H10ClNO5

PRODUCTS

生成物

1
结构：CC1CC(=O)NN=C1c1ccc(Cl)c([N+](=O)[O-])c1
HCID2874432

6-(4-chloro-3-nitrophenyl)-5-methyl-4,5-dihydropyridazin-3(2H)-one

C11H10ClN3O3

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(=O)O
溶剂HCID176

Acetic Acid

C2H4O2

PROCEDURE

实验过程

920 g of 3-(4-chloro-3-nitrobenzoyl)-butyric acid are added to a mixture of 6.8 1 of acetic acid and 499 g of hydrazine hydrate, and the mixture is stirred for 2 hours at 95°-100°. It is poured into ice water, and filtration gives 6-(4-chloro-3-nitrophenyl)-5-methyl-2,3,4,5-tetrahydropyridazin-3-one, m.p. 186°-188°.