m-Chloroperbenzoic acid → HCID 14722320, compound

HRID 1031671Notes

Reaction equation

HRID 1031671 reaction equation
[CH3:1][S:2]([NH:5][C:6]1[C:18]([O:19][C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)=[CH:17][C:9]2[C:10](=[O:16])[C:11]([S:14][CH3:15])=[CH:12][O:13][C:8]=2[CH:7]=1)(=[O:4])=[O:3].ClC1C=CC=C(C(OO)=[O:34])C=1>>[CH3:15][S:14]([C:11]1[C:10](=[O:16])[C:9]2[CH:17]=[C:18]([O:19][C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)[C:6]([NH:5][S:2]([CH3:1])(=[O:3])=[O:4])=[CH:7][C:8]=2[O:13][CH:12]=1)=[O:34]

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 14722319HCID 14722319, compound

Product 1

HCID 14722320HCID 14722320, compound

Procedure

7-Methylsulfonylamino-3-methylthio-6-phenoxy-4H-1-benzopyran-4-one was reacted with m-chloroperbenzoic acid in equimolar amounts to obtain 3-methylsulfinyl-7-methylsulfonylamino-6-phenoxy-4H-1-benzopyran-4-one [Compound No. 5].

Sources & evidence

ORD record
ord-ac394e8629f44d8287570c2f07de6b72
Source dataset
uspto-grants-1990_09
Patent number
US04954518

Reaction notes

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