m-Chloroperbenzoic acid → HCID 22166890, compound

HRID 1031883Notes

Reaction equation

HRID 1031883 reaction equation
[O:1]1[CH2:6][CH2:5][N:4]([C:7]2[N:12]=[CH:11][N:10]=[C:9]([CH2:13][S:14][C:15]3[NH:19][C:18]4=[CH:20][S:21][CH:22]=[C:17]4[N:16]=3)[CH:8]=2)[CH2:3][CH2:2]1.ClC1C=CC=C(C(OO)=[O:31])C=1>>[O:1]1[CH2:6][CH2:5][N:4]([C:7]2[N:12]=[CH:11][N:10]=[C:9]([CH2:13][S:14]([C:15]3[NH:16][C:17]4=[CH:22][S:21][CH:20]=[C:18]4[N:19]=3)=[O:31])[CH:8]=2)[CH2:3][CH2:2]1

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 22166981HCID 22166981, compound

Product 1

HCID 22166890HCID 22166890, compound

Procedure

180 mg of 2-(6-morpholino-4-pyrimidinylmethylthio)-1H-thieno[3,4-d]imidazole were oxidized with m-chloroperbenzoic acid in analogy to Example 1g. 140 mg of 2-(6-morpholino-4-pyrimidinylmethylsulfinyl)-1H-thieno[3,4-d]imidazole were obtained (melting point 107° C. [decomposition]).

Sources & evidence

ORD record
ord-7a78b8774786439bbd96156b4d550327
Source dataset
uspto-grants-1990_09
Patent number
US04956366

Reaction notes

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