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Potassium Iodide → HCID 14556323、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Potassium Iodide | HCID 4875 | — |
| 反応物 | Sodium Carbonate | HCID 10340 | — |
| 反応物 | 3-Bromo-1-propanol | HCID 12308 | — |
| 反応物 | 1,1'-(Bromomethylene)bis(4-fluorobenzene) | HCID 67665 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | HCID 14556323 | HCID 14556323 | 68.8% |
反応手順
A mixture of 36.9 g (0.130 mole) of bromobis(4-fluorophenyl)methane, 21.7 g (0.156 mole) of 3-bromopropanol, 16.6 g (0.156 mole) of sodium carbonate and a few potassium iodide crystals were heated to 130° C. for 16 hours. After cooling, the reaction mixture was diluted with water and extracted with ether. The ethereal phase was washed with water, dried on sodium sulfate and then concentrated to dryness. Distillation of the residue yielded 30.5 g (yield: 68%) of the desired propane.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04957927 |
| 出典データセット | uspto-grants-1990_09 |
| ORD ID | ord-a0e664139cd24e3b8ea7721e27018984 |
| 出典メモ | uspto-grants-1990_09 |