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HRID1032523

反应详情

EQUATION

反应方程式

HRID 1032523 的结构方程式

REACTANTS

反应物

3
结构：CC(C)OC(C)C
HCID7914

Isopropyl ether

C6H14O

结构：CN(C)C(OC(C)(C)C)N(C)C
HCID79885

tert-Butoxy bis(dimethylamino)methane

C9H22N2O

结构：Cc1ccc([N+](=O)[O-])c2[nH]ncc12
HCID22166018

4-Methyl-7-nitro-1H-indazole

C8H7N3O2

PRODUCTS

生成物

1
结构：CN(C)C=Cc1ccc([N+](=O)[O-])c2[nH]ncc12
HCID54098844

未命名化合物

收率 94.8%

PROCEDURE

实验过程

17.7 g of 4-methyl-7-nitro-1H-indazole [Chem. Ber. 37: 2556 (1904)] and 68.0 g of tertbutoxybis(dimethylamino)methane are heated to 80° C. for 45 minutes, combined with diisopropyl ether, suctioned off, and washed with diisopropyl ether, thus producing 22.0 g of N,N-dimethyl-N-[2-(7-nitro-1H-indazol-4-yl)ethenyl]amine, mp 255° C.

WORKUP

后处理

  1. washwashed with diisopropyl ether