HCID 86744232, compound → HCID 86744231, compound

HRID 1032672Notes

Reaction equation

HRID 1032672 reaction equation
[N+:1]([C:4]1[CH:25]=[CH:24][C:7]([CH2:8][CH2:9][CH2:10][NH:11][CH2:12][CH2:13][CH2:14][C:15]2[CH:20]=[CH:19][C:18]([N+:21]([O-])=O)=[CH:17][CH:16]=2)=[CH:6][CH:5]=1)([O-])=O>C(O)C.[Pd]>[NH2:1][C:4]1[CH:5]=[CH:6][C:7]([CH2:8][CH2:9][CH2:10][NH:11][CH2:12][CH2:13][CH2:14][C:15]2[CH:16]=[CH:17][C:18]([NH2:21])=[CH:19][CH:20]=2)=[CH:24][CH:25]=1

Participants

4

Reactant 1

HCID 86744232HCID 86744232, compound

Product 1

HCID 86744231HCID 86744231, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

A solution of N,N-bis-(4-nitrophenethyl)methylamine (1.2 g, 3.6 mmol) in ethanol (50 ml) containing 5% Pd/C (0.15 g) was stirred under a hydrogen atmosphere (50 p.s.i.) for 4 hours. The reaction mixture was filtered and the solvent evaporated to give the title compound as an oil, yield 1.0 g, which was used directly without further purification.

Workup

  1. filtrationThe reaction mixture was filtered
  2. customthe solvent evaporated

Sources & evidence

ORD record
ord-4a767b3e472a4fbc9c93ad05a0f97f28
Source dataset
uspto-grants-1990_09
Patent number
US04959366

Reaction notes

Loading…