HCID 10491689, compound → HCID 10632494, compound

HRID 1032692Notes

Reaction equation

HRID 1032692 reaction equation
[CH3:1][O:2][C:3]1[CH:19]=[CH:18][C:6]([O:7][C:8]2[CH:9]=[N+:10]([O-])[CH:11]=[CH:12][C:13]=2[N+:14]([O-])=O)=[CH:5][CH:4]=1.[H][H]>O=[Pt]=O.C(O)C>[CH3:1][O:2][C:3]1[CH:19]=[CH:18][C:6]([O:7][C:8]2[CH:9]=[N:10][CH:11]=[CH:12][C:13]=2[NH2:14])=[CH:5][CH:4]=1

Participants

5

Reactant 2

HCID 10491689HCID 10491689, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 10632494HCID 10632494, compound

Reagents, catalysts & solvents 2

HCID 345198Adams' catalystCatalystHCID 702EthanolSolvent

Procedure

To 250 ml ethanol in a 500 ml Parr hydrogenation bottle, were added 3-(4-methoxyphenoxy)-4-nitropyridine-1-oxide (7.9 g) and 0.4 g PtO2. After shaking for two hours at fifty psi of hydrogen, the mixture was filtered and concentrated to 5.8 g of oil.

Workup

  1. filtrationthe mixture was filtered
  2. concentrationconcentrated to 5.8 g of oil

Sources & evidence

ORD record
ord-bad1c5014c7a4fe08204f4b628b010ed
Source dataset
uspto-grants-1990_09
Patent number
US04959377

Reaction notes

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