HRID1032865

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6348

Carbon disulfide

CS2

HCID14798

Sodium Hydroxide

HNaO

HCID16316

Dipentylamine

C10H23N

HCID83301

Tungsten(VI) chloride

Cl6W

PRODUCTS

生成物

结构：CCCCCN(CCCCC)C(=S)[S-].CCCCCN(CCCCC)C(=S)[S-].CCCCCN(CCCCC)C(=S)[S-].CCCCCN(CCCCC)C(=S)[S-].CCCCCN(CCCCC)C(=S)[S-].CCCCCN(CCCCC)C(=S)[S-].[W+6]

HCID178446353

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

2 次

PROCEDURE

实验过程

0.576 kg of granulated caustic soda is added to 8 liters of anhydrous methanol and the mixture is stirred until all solid material has dissolved. 2.26 kg of diamylamine are added to the solution and 0.88 liter of carbon disulfide is introduced over a period of 2 hours. The mixture is stirred for a further 3 hours at 25° C. and a solution of 0.952 kg of tungsten hexachloride in 2.4 liters of anhydrous methanol is then added over a period of one hour and the mixture is stirred for an additional 3 hours.

WORKUP

后处理

dissolutionhas dissolved
additionis introduced over a period of 2 hours
stirringThe mixture is stirred for a further 3 hours at 25° C.
stirringthe mixture is stirred for an additional 3 hours

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-509824005bfb4f039a021a270549f27e
来源数据集: uspto-grants-1994_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05308519
来源说明: uspto-grants-1994_05

反应 SMILES

[OH-].[Na+].[CH2:3]([NH:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH2:4][CH2:5][CH2:6][CH3:7].[C:14](=[S:16])=[S:15].[W:17](Cl)(Cl)(Cl)(Cl)(Cl)Cl>CO>[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[W+6:17]