Sodium → HCID 10262182, compound

HRID 1033028Notes

Reaction equation

HRID 1033028 reaction equation
[CH3:1][C:2]1[NH:7][C:6](=[O:8])[C:5]([N+:9]([O-:11])=[O:10])=[CH:4][C:3]=1[S:12][CH2:13]C.[Na].C(SC(C(=O)C)CO)C>>[CH3:1][C:2]1[NH:7][C:6](=[O:8])[C:5]([N+:9]([O-:11])=[O:10])=[CH:4][C:3]=1[S:12][CH3:13]

Participants

4

Reactant 3

HCID 5360545SodiumHCID 10036165HCID 10036165, compoundHCID 19086255HCID 19086255, compound

Product 1

HCID 10262182HCID 10262182, compound

Procedure

The corresponding 6-methyl-5-ethylthio-3-nitropyridin-2(1H)-one, prepared in a similar way, but starting with the sodium salt of 2-ethylthio-3-oxo-1-butanol had m.p. 190°-191° C. (Yield 43.6%).

Sources & evidence

ORD record
ord-061bd12efdb048b7a853319af85c9b62
Source dataset
uspto-grants-1994_05
Patent number
US05308854

Reaction notes

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