HuagongsheHuagongshe Chemistry Print Report · For research reference only
2'-Bromoacetophenone → 1-(4'-Methyl[1,1'-biphenyl]-2-yl)ethanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2'-Bromoacetophenone | HCID 75060 | — |
| Reactant | Stannane, trimethyl(4-methylphenyl)- | HCID 617834 | — |
| Product | 1-(4'-Methyl[1,1'-biphenyl]-2-yl)ethanone | HCID 9837211 | — |
Reaction Steps
Prepared from 4-methylphenyltrimethylstannane (Example 69, Step A) and 2'-bromoacetophenone by the procedure described in Example 69, Step B. 1H NMR (200 MHz,CDCl3): 1.98 (s,3H), 2.37 (s,3H), 7.20 (s,4H), 7.3-7.5 (m,4H). FAB-MS: calculated for C15H14O 210; found 211 (M+H,100%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05310737 |
| Source dataset | uspto-grants-1994_05 |
| ORD ID | ord-0ef530f687484adb8ed2531dda6f22bf |
| Source note | uspto-grants-1994_05 |