HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethoxysilane → HCID 86664259, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethoxysilane | HCID 13830 | — |
| Reactant | 3-(But-3-enyloxy)cyclooct-1-yne | HCID 86664258 | — |
| Product | HCID 86664259 | HCID 86664259 | 97% |
Reaction Steps
The compound 3 (1.28 g, 7.18 mmol) is mixed with triethoxysilane (3.6 ml). The Karstedt catalyst is added very slowly in a catalytic amount (10 drops). The reaction takes place at 45° C. over three days. The product is purified by flash chromatography (100% AcOEt) to give a brown liquid (2.4 g, 7 mmol, 97%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08546598B2 |
| Source dataset | uspto-grants-2013_10 |
| ORD ID | ord-b7d28a078aaf403dac6402008201e627 |
| Source note | uspto-grants-2013_10 |