HuagongsheHuagongshe Chemistry Print Report · For research reference only
Itaconic acid → Lactic acid itaconic acid epsilon-caprolactone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Itaconic acid | HCID 811 | — |
| Reactant | Pentaerythritol | HCID 8285 | — |
| Reactant | epsilon-CAPROLACTONE | HCID 10401 | — |
| Reactant | Stannous cation | HCID 104883 | — |
| Reactant | L-Lactic Acid | HCID 107689 | — |
| Product | Lactic acid itaconic acid epsilon-caprolactone | HCID 86597550 | — |
Reaction Steps
The polymerisation was performed like in Example 1, but the amounts of the ingredients were 794.7 g of aqueous L-lactic acid (81 mole-%), 72.5 g of itaconic acid (7 mole-%), 110.7 g of ε-caprolactone (10 mole-%), 22.0 g of pentaerythritol (2 mole-%) and 0.39 g of tin(II) octoate, and the polymerisation time was 26 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08563664B2 |
| Source dataset | uspto-grants-2013_10 |
| ORD ID | ord-c841103ab0fc40968928bd54a36c5fc9 |
| Source note | uspto-grants-2013_10 |