Benzene, 1,1'-(methylsilylene)bis- → ({bicyclo[2.2.1]hept-5-en-2-yl}methoxy)(methyl)diphenylsilane

HRID 1049949Notes

Reaction equation

HRID 1049949 reaction equation
[C:1]12(CO)[CH2:7][CH:4]([CH2:5][CH2:6]1)[CH:3]=[CH:2]2.[CH3:10][SiH:11]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.C[C:25](C)([O-:27])C.[K+]>>[CH:1]12[CH2:7][CH:4]([CH:3]=[CH:2]1)[CH2:5][CH:6]2[CH2:25][O:27][Si:11]([CH3:10])([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1

Participants

4

Reactant 3

HCID 69893Benzene, 1,1'-(methylsilylene)bis-HCID 202731456814-81-9HCID 23665647Potassium tert-butoxide

Product 1

HCID 23448607({bicyclo[2.2.1]hept-5-en-2-yl}methoxy)(methyl)diphenylsilane

Procedure

and reacting norbornene methanol (IB) with methyldiphenylsilane in the presence of a suitable solvent and potassium tert-butoxide to obtain (bicyclo[2.2.1]hept-5-en-2-ylmethoxy)(methyl)diphenylsilane (VB) of at least 99.5 percent purity.

Sources & evidence

ORD record
ord-54a9faded0e9486c8595292d63b7d3e4
Source dataset
uspto-grants-2016_07
Patent number
US09382271B2

Reaction notes

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