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HRID1051180

反应详情

EQUATION

反应方程式

HRID 1051180 的结构方程式

REACTANTS

反应物

2
结构：BrBr
HCID24408

Bromine

Br2

结构：Nc1c([N+](=O)[O-])cccc1[N+](=O)[O-]
HCID69070

2,6-Dinitroaniline

C6H5N3O4

PRODUCTS

生成物

1
结构：Nc1c([N+](=O)[O-])cc(Br)cc1[N+](=O)[O-]
HCID3746608

4-bromo-2,6-dinitroaniline

C6H4BrN3O4

收率 86%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(=O)O
溶剂HCID176

Acetic Acid

C2H4O2

PROCEDURE

实验过程

A mixture comprising 247.5 g (1.35 mol) 2,6-dinitroaniline, 2.5 L acetic acid and 250 mL bromine was heated to 100° C. for a few minutes. After cooling, the formed crystals were filtered and washed with n-hexane to give 304 g (86%) of the title compound.

WORKUP

后处理

  1. temperatureAfter cooling
  2. filtrationthe formed crystals were filtered
  3. washwashed with n-hexane