HuagongsheHuagongshe Chemistry Print Report · For research reference only
(2-Bromo-5-nitrophenyl)methanol → 2-Bromo-5-nitrobenzaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (2-Bromo-5-nitrophenyl)methanol | HCID 18671373 | — |
| Reactant | HCID 178418287 | HCID 178418287 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 2-Bromo-5-nitrobenzaldehyde | HCID 11138942 | — |
Reaction Steps
To a stirring solution of (2-bromo-5-nitrophenyl) methan-1-ol (1 eq) in methylene chloride (0.1 M) at room temperature was added pyridinium chlorochromate (2 eq). After 2 hr the reaction mixture was filtered through celite and the product was purified by flash chromatography (15% EtOAc/Hexane). EI-MS m/z 230 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06514964B1 |
| Source dataset | uspto-grants-2003_02 |
| ORD ID | ord-fbc384056f684647b99603fc08343c51 |
| Source note | uspto-grants-2003_02 |