HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,2-Epoxycyclododeca-5,9-diene → 13-Oxabicyclo[10.1.0]tridecane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,2-Epoxycyclododeca-5,9-diene | HCID 79135 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | 13-Oxabicyclo[10.1.0]tridecane | HCID 9248 | — |
| Product | Cyclododecanone | HCID 13246 | — |
| Product | Cyclododecanol | HCID 15595 | — |
Reaction Steps
Further, Neftekhimiya, 16 (1), 114-119 (1976) discloses a catalytic reaction of 1,2-epoxy-5,9-cyclododecadiene with hydrogen in the presence of a palladium-carried catalyst at a reaction temperature of 140° C. under a hydrogen gas pressure of 8,106 kPa (80 atmospheres). In this reaction, epoxycyclododecane was produced in a yield of 49.5%, cyclododecanol in a yield of 33.3%, and cyclododecanone in a yield of 3.4%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06515185B1 |
| Source dataset | uspto-grants-2003_02 |
| ORD ID | ord-6f5fb04ddc0b43c5accf30f57e194f3d |
| Source note | uspto-grants-2003_02 |