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1-Chloro-2,2-dimethylpropane → HCID 178445855、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Chloro-2,2-dimethylpropane | HCID 12956 | — |
| 反応物 | Magnesium | HCID 5462224 | — |
| 反応物 | HCID 178418809 | HCID 178418809 | — |
| 反応物 | HCID 178445854 | HCID 178445854 | — |
| 溶媒 | Hexane | HCID 8058 | — |
| 生成物 | HCID 178445855 | HCID 178445855 | — |
反応手順
CrCl3(THF)3 (a product of Aldrich Co.) and 2,2-dimethylpropyl magnesium chloride (synthesized from 1-chloro-2,2-dimethylpropane, a product of Aldrich Co. and magnesium, a product of Wako Pure Chemicals Co.) were reacted according to a method described in J. Chem. Soc., Dalton Trans., 770 (1973) to prepare tetrakis(2,2-dimethylpropyl)chromium(III). This compound was dissolved in distillation-purified hexane to obtain a solution of 0.10 mol/liter, 5.20 g/liter.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06518375B1 |
| 出典データセット | uspto-grants-2003_02 |
| ORD ID | ord-8d0255e59b5843d1bccc872339a8b7e0 |
| 出典メモ | uspto-grants-2003_02 |