1-Chloro-2,2-dimethylpropane → HCID 178445855, compound

HRID 1059048Notes

Reaction equation

HRID 1059048 reaction equation
CC(C)(C)C[Mg]Cl.ClCC(C)(C)C.[Mg].[CH3:15][C:16]([CH3:35])([CH3:34])[CH2:17][Cr-:18]([CH2:29][C:30]([CH3:33])([CH3:32])[CH3:31])([CH2:24][C:25]([CH3:28])([CH3:27])[CH3:26])[CH2:19][C:20]([CH3:23])([CH3:22])[CH3:21]>CCCCCC>[CH3:21][C:20]([CH3:23])([CH3:22])[CH2:19][Cr:18]([CH2:17][C:16]([CH3:35])([CH3:34])[CH3:15])([CH2:24][C:25]([CH3:28])([CH3:27])[CH3:26])[CH2:29][C:30]([CH3:31])([CH3:32])[CH3:33]

Participants

6

Reactant 4

HCID 129561-Chloro-2,2-dimethylpropaneHCID 5462224MagnesiumHCID 178418809HCID 178418809, compoundHCID 178445854HCID 178445854, compound

Product 1

HCID 178445855HCID 178445855, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

CrCl3(THF)3 (a product of Aldrich Co.) and 2,2-dimethylpropyl magnesium chloride (synthesized from 1-chloro-2,2-dimethylpropane, a product of Aldrich Co. and magnesium, a product of Wako Pure Chemicals Co.) were reacted according to a method described in J. Chem. Soc., Dalton Trans., 770 (1973) to prepare tetrakis(2,2-dimethylpropyl)chromium(III). This compound was dissolved in distillation-purified hexane to obtain a solution of 0.10 mol/liter, 5.20 g/liter.

Workup

  1. custom) were reacted
  2. customto obtain a solution of 0.10 mol/liter, 5.20 g/liter

Sources & evidence

ORD record
ord-8d0255e59b5843d1bccc872339a8b7e0
Source dataset
uspto-grants-2003_02
Patent number
US06518375B1

Reaction notes

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