Hydrogen Peroxide → HCID 69314014, compound

HRID 1064002Notes

Reaction equation

HRID 1064002 reaction equation
[N+:1]([C:4]1[CH:27]=[CH:26][C:7]([CH2:8][O:9][C:10]([NH:12][C:13]2[CH:25]=[CH:24][C:16]3[S:17][C:18]4[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=4[C:15]=3[CH:14]=2)=[O:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].[OH:28]O>C(O)(=O)C>[O:28]=[S:17]1[C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=2[C:15]2[CH:14]=[C:13]([NH:12][C:10]([O:9][CH2:8][C:7]3[CH:26]=[CH:27][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][CH:6]=3)=[O:11])[CH:25]=[CH:24][C:16]1=2

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 693158012-(4-Nitrobenzoxycarbonylamino)dibenzothiophene

Product 1

HCID 69314014HCID 69314014, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Conditions

Temperature
60 °C

Procedure

2-(4-Nitrobenzoxycarbonylamino)dibenzothiophene (Example 1; 364 mg, 1.0 mmol) was suspended in a mixture of glacial acetic acid (5.0 ml) and 30% hydrogen peroxide (565 mg, 5 mmol) and the mixture was warmed at 60° C. for 2 hours. The suspension of the title compound was filtered and air dried. TLC: (2:1; EtOAc:isohexane) Rf=0.30.

Sources & evidence

ORD record
ord-3e9476de57944e8282e1d07575d66224
Source dataset
uspto-grants-2005_11
Patent number
US06967216B2

Reaction notes

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