Chlorine → HCID 20541100, compound

HRID 1065030Notes

Reaction equation

HRID 1065030 reaction equation
[CH3:1][O:2][C:3](=[O:11])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([I:10])[CH:5]=1.[Cl:12]Cl>C(Cl)(Cl)Cl>[Cl-:12].[Cl-:12].[CH3:1][O:2][C:3](=[O:11])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([I:10])[CH:5]=1

Participants

4

Reactant 2

HCID 24526ChlorineHCID 69258Methyl 3-iodobenzoate

Product 1

HCID 20541100HCID 20541100, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

A solution of 5.0 g methyl-m-iodobenzoate in 70 ml chloroform was cooled to 0°-10° and treated with gaseous chlorine for 1 hour. The resulting yellow solution was evaporated to afford 6.2 g methyl-m-iodobenzoate dichloride as yellow needles, mp=108°-110°. IR: 5.83, 7.80, 8.00, 8.90, 9.18, 10.52, 11.12, 12.39, and 13.48.

Workup

  1. customThe resulting yellow solution was evaporated

Sources & evidence

ORD record
ord-430ff9281a904a6f9c93127fe7a25470
Source dataset
uspto-grants-1982_05
Patent number
US04328162

Reaction notes

Loading…