Potassium hexafluoroantimonate(1-) → Diphenyliodonium hexafluoroantimonate

HRID 1065210Notes

Reaction equation

HRID 1065210 reaction equation
Cl([O-])(=O)(=O)=O.[C:6]1([I+:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[F:19][Sb-:20]([F:25])([F:24])([F:23])([F:22])[F:21].[K+]>CO>[F:19][Sb-:20]([F:25])([F:24])([F:23])([F:22])[F:21].[C:13]1([I+:12][C:6]2[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=2)[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1

Participants

4

Reactant 2

HCID 16688490Potassium hexafluoroantimonate(1-)HCID 19708536Diphenyliodanium perchlorate

Product 1

HCID 16701408Diphenyliodonium hexafluoroantimonateYield 86.1%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Conditions

Temperature
25 °C

Procedure

A mixture of 4 parts of diphenyliodonium perchlorate and 2.8 parts of potassium hexafluoroantimonate and 100 parts of methanol was stirred for 1 hour at 25° C. The resulting mixture was then filtered and the methanol solution evaporated to produce a solid having a melting point of 77°-87° C. Based on method of preparation there was obtained an 86.1% yield of diphenyliodonium hexafluoroantimonate.

Workup

  1. filtrationThe resulting mixture was then filtered
  2. customthe methanol solution evaporated
  3. customto produce a solid
  4. customBased on method of preparation

Sources & evidence

ORD record
ord-287899fa7a1e477fbc1e50b7b33ca42c
Source dataset
uspto-grants-1982_05
Patent number
US04329300

Reaction notes

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