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HRID1066278

反应详情

EQUATION

反应方程式

HRID 1066278 的结构方程式

REACTANTS

反应物

1
结构：CC(=O)O[C@@H]1C[C@@H](OC2CCCCO2)[C@@H](CO[Si](C)(C)C(C)(C)C)C1CCCCCCCCC(=O)OC(C)C
HCID131722605

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)O[C@@H]1C[C@@H](OC2CCCCO2)[C@@H](CO)C1CCCCCCCCC(=O)OC(C)C
HCID70147894

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：C1CCOC1
溶剂HCID8028

Tetrahydrofuran

C4H8O

结构：CCCC[N+](CCCC)(CCCC)CCCC.[F-]
溶剂HCID2724141

Tetra-n-butylammonium fluoride

C16H36FN

PROCEDURE

实验过程

To the solution of the compound (13-3) (4.05 g) in THF(8 ml), tetrabutylammonium fluoride (1M, THF solution, 8.51 ml) was added at room temperature and the mixture was left overnight. The crude product obtained by the conventional treatment was purified by silica gel chromatography (n-hexane/ethyl acetate=6/4) to give the titled compound (13-4).

WORKUP

后处理

  1. customThe crude product obtained by the conventional treatment
  2. customwas purified by silica gel chromatography (n-hexane/ethyl acetate=6/4)