Sulfate Ion → Guanine

HRID 1066392Notes

Reaction equation

HRID 1066392 reaction equation
S([O-])([O-])(=O)=O.[NH2:6][C:7]1[N:12]=[C:11]([NH2:13])[C:10]([NH:14][CH:15]=O)=[C:9]([OH:17])[N:8]=1>>[NH:8]1[C:9](=[O:17])[C:10]2[NH:14][CH:15]=[N:13][C:11]=2[N:12]=[C:7]1[NH2:6]

Participants

3

Reactant 2

HCID 1117Sulfate IonHCID 178508810N-(2,6-diamino-4-oxo-1H-pyrimidin-5-yl)formamide

Product 1

HCID 135398634Guanine

Procedure

In the process based on TAHP sulfate described above, 2,4-diamino-5-formylamino-6-hydroxypyrimidine (referred to as DAFHP below) is passed through as an intermediate, which is reacted in situ to produce guanine.

Workup

  1. customis reacted in situ

Sources & evidence

ORD record
ord-6af559b05bd44b89982e80a76db6c0ee
Source dataset
uspto-grants-2001_06
Patent number
US06242599B1

Reaction notes

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