4-Ethoxybenzoic acid → 3-BROMO-4-ETHOXYBENZOIC ACID

HRID 1067284Notes

Reaction equation

HRID 1067284 reaction equation
[CH2:1]([O:3][C:4]1[CH:12]=[CH:11][C:7]([C:8]([OH:10])=[O:9])=[CH:6][CH:5]=1)[CH3:2].[Br:13]Br>C(Cl)(Cl)Cl>[Br:13][C:5]1[CH:6]=[C:7]([CH:11]=[CH:12][C:4]=1[O:3][CH2:1][CH3:2])[C:8]([OH:10])=[O:9]

Participants

4

Reactant 2

HCID 120934-Ethoxybenzoic acidHCID 24408Bromine

Product 1

HCID 31161943-BROMO-4-ETHOXYBENZOIC ACID

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

To a solution of 4ethoxybenzoic acid (3.6 g, 0.022 mol) in chloroform (60 ml) was added bromine (1.13 ml, 0.022 mol) in chloroform (20 ml) dropwise. After stirring overnight at room temperature the precipitate was filtered off and dried to afford the title compound as a white solid.

Workup

  1. filtrationwas filtered off
  2. customdried

Sources & evidence

ORD record
ord-f98146b56e02444fa978c9f341886fd9
Source dataset
uspto-grants-2001_06
Patent number
US06248754B1

Reaction notes

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