Sodium Cyanide → HCID 21195131, compound

HRID 1067886Notes

Reaction equation

HRID 1067886 reaction equation
Br[C:2]1[N:7]=[C:6]([C:8]2[CH:13]=[C:12]([C:14]3[CH:19]=[CH:18][C:17]([O:20][CH3:21])=[CH:16][CH:15]=3)[CH:11]=[C:10]([C:22]3[CH:27]=[CH:26][CH:25]=[CH:24][N:23]=3)[N:9]=2)[CH:5]=[CH:4][CH:3]=1.[C-:28]#[N:29].[Na+]>CN(C)C=O>[C:28]([C:2]1[N:7]=[C:6]([C:8]2[CH:13]=[C:12]([C:14]3[CH:19]=[CH:18][C:17]([O:20][CH3:21])=[CH:16][CH:15]=3)[CH:11]=[C:10]([C:22]3[CH:27]=[CH:26][CH:25]=[CH:24][N:23]=3)[N:9]=2)[CH:5]=[CH:4][CH:3]=1)#[N:29]

Participants

4

Reactant 2

HCID 8929Sodium CyanideHCID 21195132HCID 21195132, compound

Product 1

HCID 21195131HCID 21195131, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

6-Cyano-4′-(4-methoxyphenyl)-2,2′:6′,2″-terpyridine is prepared by the method of example 27 from 6-bromo-4′-(4-methoxyphenyl)-2,2′:6′,2″-terpyridine (0.0745 mol), cuprous cyanide (0.296 mol), sodium cyanide (0.297 mol), and dimethylformamide (300 ml).

Sources & evidence

ORD record
ord-718098f05d734e4eb23731d5cef36ca3
Source dataset
uspto-grants-2001_06
Patent number
US06248870B1

Reaction notes

Loading…