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HRID1068095

反应详情

EQUATION

反应方程式

HRID 1068095 的结构方程式

REACTANTS

反应物

3
结构：NCCCN(CCCN)CCCN
HCID547030

Tris(3-aminopropyl)amine

C9H24N4

结构：CC(=O)c1cc(N=C=O)cc(C(C)=O)c1
HCID15541285

未命名化合物

结构：CC(=O)c1cc(NC(=O)NCCCN(CCCNC(=NNC(=N)N)Nc2cc(C(C)=NNC(=N)N)cc(C(C)=NNC(=N)N)c2)CCCNC(=NNC(=N)N)Nc2cc(C(C)=NNC(=N)N)cc(C(C)=NNC(=N)N)c2)cc(C(C)=O)c1.Cl.Cl.Cl.Cl.Cl.Cl.Cl
HCID178466969

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)c1cc(NC(=O)NCCCN(CCCNC(=O)Nc2cc(C(C)=O)cc(C(C)=O)c2)CCCNC(=O)Nc2cc(C(C)=O)cc(C(C)=O)c2)cc(C(C)=O)c1
HCID21195014

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：C1CCOC1
溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

Compound 36, FIG. 7H.36: 3,5-Diacetylphenyl isocyanate (0.4 g) and tris(3-aminopropyl)amine (0.12 g) in tetrahydrofuran (5 mL) were stirred at r.t. for 30 min. Filtration gave 0.32 g of tris(3-[([(3,5-diacetylphenyl)-amino]carbonyl)amino]propyl)amine, mp 147-8 C. This hexa-ketone (0.4 g) and aminoguanidine dihydrochloride (0.49 g) were heated in methanol (3 mL) for 4 hours. Addition of ethanol and filtration gave 0.58 g of tris(3-[([(3,5-diacetylphenyl)amino]carbonyl)amino]propyl)amine hexakis(amidinohydrazone) heptahydrochloride (Compound 36) as the dihydrate hemi-ethanolate, mp 250-1° C. (dec).

WORKUP

后处理

  1. filtrationFiltration